Charge-Transfer Complexes of Benzo〔b〕thiophene with σ-and π-Electron Acceptors

• Mohamad M. Ayad

書誌事項

タイトル別名

• Charge-Transfer Complexes of Benzo b th

抄録

The spectrophotometric properties of the charge-transfer (CT) complexes of benzo[b]thiophene with iodine at 24 °C in different solvents such as cychlohexane, carbon tetrachloride, chloroform, dichloromethane, and 1,2-dichloroethane are studied. In addition the spectrophotometric and thermodynamic properties of the CT complexes of benzo[b]thiophene with tetracyanoethylene, chloranil, 2,3-dichloro-5,6-dicyano-p-benzoquinone and 7,7,8,8,-tetracyanoquinodimethane are studied. The results show that the equilibrium and the thermodynamic parameters and the wavelengths of the maximum absorption bands (λmax) of the complexes vary markedly with the solvent. The ionization potential and the donor sites of benzo[b]thiophene are also determined and discussed.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 70 (10), 2369-2373, 1997-10

  Tokyo : Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1523669553264830592
• NII論文ID: 10008923816
• NII書誌ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.70.2369
• NDL書誌ID: 4326340
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4326340
• Web Site: https://academic.oup.com/bcsj/article-pdf/70/10/2369/56197609/bcsj.70.2369.pdf
• 本文言語コード: en
• NDL 雑誌分類:
  • ZP1(科学技術--化学・化学工業)
• データソース種別:
  • NDL
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