Selective N-Alkylation of Imidazole with Alcohols over Calcined Layered Double Hydroxides

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Abstract

Vapor-phase <i>N</i>-alkylation syntheses of imidazole were carried out with MeOH and EtOH over a series of calcined Mg<sup>II</sup>–Al<sup>III</sup> layered double hydroxides (LDHs) selectively produced in high yields of <i>N</i>-methyl (70%) and <i>N</i>-ethyl (63%) imidazoles only on the 3 : 1 atomic ratio of Mg<sup>II</sup>–Al<sup>III</sup> calcined LDH. Attempts on C-alkylation and dialkylation reactions over the same catalysts proved to be unsuccessful.

Journal

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 70(11), 2829-2831, 1997-11-15

    The Chemical Society of Japan

References:  16

  • <no title>

    ROTH H. J.

    Pharm. Chemisty 1, 219, 1988

    Cited by (1)

  • <no title>

    ONO Y.

    Stud. Surf. Sci. Catal. 94, 697, 1995

    Cited by (1)

  • <no title>

    SAITO H.

    J. Am. Chem. Soc. 95, 324, 1973

    Cited by (1)

  • <no title>

    TAKEUCHI Y.

    J. Org. Chem. 43, 3565, 1978

    Cited by (1)

  • <no title>

    CAVANI F.

    Catal. Today 11, 173, 1991

    Cited by (38)

  • <no title>

    SANTHANALAKHSMI J.

    Appl. Catal., A: General 147, 69, 1996

    Cited by (1)

  • <no title>

    VELU S.

    Appl. Catal., A: General 119, 241, 1994

    Cited by (1)

  • <no title>

    RAJA T.

    J. Mater. Sci. Lett. 15, 710, 1996

    Cited by (1)

  • <no title>

    BRINDLEY G. W.

    Am. Miner. 64, 836, 1979

    Cited by (1)

  • <no title>

    HERNANDEZ-MORENO M. J.

    Phys. Chem. Miner. 12, 34, 1985

    Cited by (3)

  • <no title>

    REICHLE W. T.

    J. Catal. 101, 352, 1986

    Cited by (5)

  • <no title>

    REICHLE W. T.

    Chemtech 1986, 58

    Cited by (2)

  • <no title>

    MIYATA S.

    Clays Clay Miner. 28, 50, 1980

    Cited by (26)

  • <no title>

    MCKENZIE A. L.

    J. Catal. 138, 547, 1992

    Cited by (3)

  • <no title>

    ONO Y.

    J. Chem. Soc., Chem. Commun. 1995, 9

    Cited by (1)

  • <no title>

    VUCELIC M.

    J. Phys. Chem. 99, 8328, 1995

    DOI  Cited by (1)

Codes

  • NII Article ID (NAID)
    10008925732
  • NII NACSIS-CAT ID (NCID)
    AA00580132
  • Text Lang
    ENG
  • Article Type
    ART
  • ISSN
    00092673
  • NDL Article ID
    4346218
  • NDL Source Classification
    ZP1(科学技術--化学・化学工業)
  • NDL Call No.
    Z53-B35
  • Data Source
    CJP  NDL  J-STAGE 
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