Solvatochromic Linear Solvation Energy Relationships for Solubility of O2 in Various Solvents.

• Che Yong

  Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology

• Tokuda Koichi

  Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology

• Ohsaka Takeo

  Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology

Bibliographic Information

Other Title

• Solvatochromic Linear Solvation Energy

Abstract

Linear solvation energy relationships for solution of O₂ in 27 solvents have been examined. Multiple linear regression equations for mole fraction solubility of O₂ are developed based on Hildebrand’s solubility parameter as well as the π*, α, and β solvatochromic parameters describing the solvent polarizability/dipolarity, hydrogen bond acidity and hydrogen bond basicity, respectively. Use of the combination of these parameters enables the medium effect on solution of O₂ to be correlated and interpreted in a conceptually simple manner.

Journal

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 71 (3), 651-656, 1998

  The Chemical Society of Japan

Keywords

• General Chemistry

Details

• CRID: 1390282679097027456
• NII Article ID: 130004150015
• NII Article ID: 10008929772
• NII Book ID: AA00580132
• DOI: 10.1246/bcsj.71.651
• ISSN: 13480634
• ISSN: 00092673
• NDL BIB ID: 4440379
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4440379
• Web Site: https://academic.oup.com/bcsj/article-pdf/71/3/651/56196433/bcsj.71.651.pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed