Tetrachlorocyclopentadienone 0-Oxide, a Facile Oxygen-Atom-Transfer Reagent : The Disproportionation of Cycloalkyldioxyl Radicals

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Photolysis of tetrachlorodiazocyclopentadiene (<b>1</b>) in oxygen-saturated hydrocarbon solvents results in the transient formation of tetrachlorocyclopentadienone <i>O</i>-oxide (<b>3</b>). This rapidly decomposes, giving rise to products derived from oxidation of the hydrocarbons. Cyclopentane, cyclopentene, cycloheptane, cycloheptene, cycloheptatriene, and indene have been studied. Cycloheptatriene and indene gave only low yields of tractable products, but the others gave the corresponding ketones and secondary alcohols as the major products. Although yields varied considerably, the ketone and alcohol products were always obtained, within experimental error, in a 1 : 1 molar ratio. This observed product ratio supports the disproportionation of cycloalkyldioxyl radicals as a crucial step.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 71(6), 1397-1400, 1998-06-15

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10008933046
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • NDL 記事登録ID
    4503967
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z53-B35
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    CJP書誌  NDL  J-STAGE 
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