Viscometric Behavior of Some Symmetrical Tetraalkylammonium Bromides in Acetonitrile + Water Mixtures at 303.15 K

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Abstract

The viscosity measurements for some symmetrical tetraalkyl ammonium bromide (R<sub>4</sub>NBr, R = CH<sub>3</sub> to C<sub>5</sub>H<sub>11</sub>) KCl, and KBr solutions in acetonitrile (ACN) + water mixtures containing 0, 10, 30, 50, 70, 90, and 100 mass% of ACN at 303.15 K have been performed. The Jones–Dole equation was used for the analysis of viscosity data of these salts. The viscosity <i>B</i>-coefficients in the entire range of ACN+water mixtures were obtained from the computerized least-squares method. The experimental criterion <i>B</i>(K<sup>+</sup>) = <i>B</i>(Cl<sup>−</sup>) = (1/2)<i>B</i>(KCl) was applied in order to obtain the ionic <i>B</i>-coefficients. The <i>B</i><sub>±</sub> coefficients are interpreted in terms of solvent structure and ion-solvent interactions in the solvents.

Journal

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 71(9), 2055-2061, 1998-09-15

    The Chemical Society of Japan

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Codes

  • NII Article ID (NAID)
    10008936106
  • NII NACSIS-CAT ID (NCID)
    AA00580132
  • Text Lang
    ENG
  • Article Type
    ART
  • ISSN
    00092673
  • NDL Article ID
    4558509
  • NDL Source Classification
    ZP1(科学技術--化学・化学工業)
  • NDL Call No.
    Z53-B35
  • Data Source
    CJP  NDL  J-STAGE 
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