Friedel–Crafts Acylation of Arenes Catalyzed by Bromopentacarbonylrhenium(I)

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  • Hiroyuki Kusama
    Department of Chemistry, Graduate School of Science, The University of TokyoHongo, Bunkyo-ku, Tokyo 113
  • Koichi Narasaka
    Department of Chemistry, Graduate School of Science, The University of TokyoHongo, Bunkyo-ku, Tokyo 113

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<jats:title>Abstract</jats:title> <jats:p>The intermolecular Friedel–Crafts acylation of aromatic compounds (such as toluene, m-xylene, and anisole) with various acid chlorides proceeds by using a catalytic amount of bromopentacarbonylrhenium(I) to afford aryl ketones. Intramolecular acylation is also catalyzed by the above-mentioned catalyst to give indanone and tetralone derivatives.</jats:p>

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