Asymmetric Hydroformylation of Olefins in Highly Crosslinked Polymer Matrixes.

• Nozaki Kyoko

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Shibahara Fumitoshi

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Itoi Yohei

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Shirakawa Eiji

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Ohta Tetsuo

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Takaya Hidemasa

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Hiyama Tamejiro

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

抄録

When polymer-immobilized chiral phosphine-phosphite–Rh(I) complexes were used, the asymmetric hydroformylation of styrene gave 2- and 3-phenylpropanals with a substrate/catalyst ratio of 2000, iso/normal ratios of 84/16 to 89/11, and 89% R enantiomeric excess of 2-phenylpropanal; these results were at the highest level in catalytic activity, regio-, and enantioselectivities. Recovery-reuse of the catalyst was examined. Asymmetric hydroformylation of vinyl acetate, (Z)-2-butene, and 3,3,3-trifluoropropene was also successfully performed with the polymer-supported catalysts.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 72 (8), 1911-1918, 1999

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204120632960
• NII論文ID: 10009138177
• NII書誌ID: AA00580132
• DOI: 10.1246/bcsj.72.1911
• ISSN: 13480634
• ISSN: 00092673
• NDL書誌ID: 4838049
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4838049
• Web Site: https://academic.oup.com/bcsj/article-pdf/72/8/1911/56197774/bcsj.72.1911.pdf
• 本文言語コード: en
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