Anomalous Electrochemical Behavior of 1,4-Benzoquinone upon the Addition of Silver Ion

• Isao Ando

• Hiroto Miyake

• Yusuke Ohki

書誌事項

タイトル別名

• Anomalous Electrochemical Behavior of 1 4 Benzoquinone upon the Addition of Silver Ion

抄録

A cyclic voltammogram of 1,4-benzoquinone showed a couple of redox waves in aqueous solution. Upon adding a trace amount of silver ion, the cyclic voltammogram exhibited an anomalous behavior: a shift of the reduction peak toward a negative potential and the appearance of a new re-oxidation peak at a much more positive potential. This anomalous electrochemical behavior was investigated in terms of both interactions in bulk and on the electrode surface using some kinds of metal-ion additives and some working-electrode materials. It is suggested that the underpotential deposition of silver ion is primarily responsible for the anomalous electrochemical behavior of 1,4-benzoquinone. This was demonstrated by a measurement of cyclic voltammograms using a silver-deposited electrode at an underpotential.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 73 (12), 2753-2757, 2000

  Tokyo : Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1521980705151049472
• NII論文ID: 10009156642
• NII書誌ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.73.2753
• NDL書誌ID: 5597312
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I5597312
• Web Site: https://academic.oup.com/bcsj/article-pdf/73/12/2753/56198487/bcsj.73.2753.pdf
• 本文言語コード: en
• NDL 雑誌分類:
  • ZP1(科学技術--化学・化学工業)
• データソース種別:
  • NDL
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