Preparation of a Kaolinite-Nylon 6 Intercalation Compound.
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- Matsumura Asako
- Department of Applied Chemistry and Kagami Memorial Laboratory for Materials Science and Technology, Waseda University
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- Komori Yoshihiko
- Department of Applied Chemistry and Kagami Memorial Laboratory for Materials Science and Technology, Waseda University
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- Itagaki Tetsuro
- Department of Applied Chemistry and Kagami Memorial Laboratory for Materials Science and Technology, Waseda University
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- Sugahara Yoshiyuki
- Department of Applied Chemistry and Kagami Memorial Laboratory for Materials Science and Technology, Waseda University
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- Kuroda Kazuyuki
- Department of Applied Chemistry and Kagami Memorial Laboratory for Materials Science and Technology, Waseda University
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Abstract
A kaolinite–nylon 6 intercalation compound was prepared by the polymerization of 6-aminohexanoic acid (AHA) in the interlayer space of kaolinite. The intercalation of AHA was achieved by a guest displacement reaction using a kaolinite–methanol intercalation compound as an intermediate. After AHA dissolved in a mixed solvent of methanol and water (1 : 3) was added to a kaolinite–methanol intercalation compound, the mixture was stirred for 3 h. The basal spacing of the product increased to 1.23 nm, indicating the intercalation of AHA molecules with a monolayer arrangement between the layers of kaolinite. AHA was polymerized by a heat treatment at 250 °C for 1 h under a nitrogen flow. Although the basal spacing of the heat-treated product slightly decreased to 1.16 nm, the spacing was larger than those of kaolinite and the kaolinite–methanol intermediate. The formation of a kaolinite-nylon 6 intercalation compound was confirmed by the appearance of IR bands due to amide I (1637 cm−1) and amide II (1550 cm−1).
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 74 (6), 1153-1158, 2001
The Chemical Society of Japan
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Details 詳細情報について
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- CRID
- 1390001204123226112
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- NII Article ID
- 10009162515
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- NII Book ID
- AA00580132
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- ISSN
- 13480634
- 00092673
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- NDL BIB ID
- 5831201
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- Text Lang
- en
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed