放電プラズマ焼結によるn型SiCの作製と熱電特性

書誌事項

タイトル別名
  • Thermoelectric Properties of n-type Silicon Carbides Prepared by Spark Plasma Sintering
  • ホウデン プラズマ ショウケツ ニ ヨル nガタ SiC ノ サクセイ ト ネツデントクセイ

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抄録

Preparation and thermoelectric properties of n-type SiC were studied. Nitrogen doping was performed by mixing 3-10 mass%Si3N4. The pellets were prepared by spark plasma sintering (SPS) at 2000°C. The crystal structure of every sintered material is cubic β-type and relative density was higher than 80%. All sintered materials showed n-type conduction and the carrier concentration increased with increasing Si3N4 concentration. Seebeck coefficient decreased and electrical conductivity increased with increasing Si3N4 concentration. Power factor was improved by the Si3N4 doping and the maximum power factor of 1.5×10−4 W/mK2 was obtained for SiC-7 mass%Si3N4 at 700°C.

収録刊行物

  • 日本金属学会誌

    日本金属学会誌 66 (3), 194-197, 2002

    公益社団法人 日本金属学会

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