排ガス中の有害物質の測定方法の検討（Ｉ）　Ｎ‐メチルアニリン，Ｎ‐エチルアニリン，ｏ‐アニシジン，ｐ‐アニシジン

• 中戸 靖子

  大阪府公害監視センター

• 西村 貴司

  大阪府公害監視センター

• 服部 幸和

  大阪府公害監視センター

• 高林 幸和

  大阪府公害監視センター

書誌事項

タイトル別名

• Study on the Determination of Toxic Chemicals in Exhaust Gas (I). N-methylaniline, N-ethylaniline, o-anisidine and p-anisidine.
• —N-methylaniline, N-ethylaniline, ο-anisidine and <I>p</I>-anisidine—
• ―N-メチルアニリン, N-エチルアニリン, οアニシジン, <I>p</I>-アニシジン―

抄録

A method for the determination of N-methylaniline, N-ethylaniline, ο-anisidine and ρ-anisidine in exhaust gas has been studied. Those compounds were sampled with a SEP-PAK^®C₁₈impregnated with phosphoric acid. Trapped substance were eluted with ethanol, extracted with dichloromethane, transferred into η-hexane and determined by capillary gas chromatography/mass spectrometry (GC/MS) or flame thermoionic detector (GC/FTID) . The most suitable pH on extraction was about 12.0. When water content of exhaust gas is more than 3%, those compounds could be sampled with absorption bottle admitting 1% hydrochloric acid aqueous solution. Detection limits, relative standard deviation and recoveries of this method were 70.8-93.3μg /m³, 6.93-17.4%, 82.3-111% with GC/MS, 45.5-105μg/m³, 2.09-15.9%, 87.3-106% with GC/FTID respectively.

収録刊行物

• 環境化学

  環境化学 5 (3), 605-616, 1995

  一般社団法人 日本環境化学会

キーワード

• N-methylaniline
• N-ethylaniline
• ο-anisidine
• <I>p</I>-anisidine
• exhaust gas

詳細情報

• CRID: 1390001204369637632
• NII論文ID: 10009670284
• NII論文ID: 10009670923
• NII書誌ID: AN10547099
• DOI: 10.5985/jec.5.605
• ISSN: 18825818
• ISSN: 09172408
• Web Site: http://www.jstage.jst.go.jp/article/jec1991/5/3/5_3_605/_pdf
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可