Pressure-Composition-Temperature Properties of Hydriding Combustion-Synthesized Mg2NiH4
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- Saita Itoko
- Department of Chemical Engineering, Osaka Prefecture University
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- Li Liquan
- College of Materials Science and Engineering, Nanjing University of Technology
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- Saito Katsushi
- TOYOTA Motor Corporation
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- Akiyama Tomohiro
- Department of Chemical Engineering, Osaka Prefecture University
書誌事項
- タイトル別名
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- Pressure-Composition-Temperature Properties of Hydriding Combustion-Synthesized Mg<SUB>2</SUB>NiH<SUB>4</SUB>
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抄録
Pure Mg2NiH4 was first prepared by Hydriding Combustion Synthesis (HCS), under which pressure and temperature were sensitively controlled. The purpose of this paper was to study “Pressure-Composition-Temperature (PCT)” properties of the HCSed product, in which hydrogen storage capacity, hydriding reaction rate, and PCT curves were mainly examined, in comparison to the commercially available product, i.e., Ingot Metallurgy product. The results showed that the HCSed Mg2NiH4 has 3.6 mass%, same as theoretical value, in hydrogen storage capacity in the first cycle just after synthesized without activation treatment, and very large reaction rate; only five minutes for full charge. Plateau pressure of the HCSed Mg2NiH4 in PCT curves also became relatively lower than the conventional one. One of the most interesting results is the high activity of our product: it stored hydrogen even at room temperature. These results appealed a possibility of new productive process of hydrogen storage alloy from the viewpoint of product property.
収録刊行物
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 43 (5), 1100-1104, 2002
公益社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390001204247818496
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- NII論文ID
- 10012323540
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- NII書誌ID
- AA1151294X
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- COI
- 1:CAS:528:DC%2BD38Xlt1enur4%3D
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- ISSN
- 13475320
- 13459678
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- NDL書誌ID
- 6180284
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可