Preparation of WC-WB-W<SUB>2</SUB>B Composites from B<SUB>4</SUB>C-W-WC Powders and their Mechanical Properties

  • Sugiyama Shigeaki
    Akita Prefectural Industrial Technology Center
  • Taimatsu Hitoshi
    Department of Materials Science and Engineering, Faculty of Engineering and Resource Science,Akita University

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  • Preparation of WC-WB-W2B Composites from B4C-W-WC Powders and their Mechanical Properties

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Abstract

Sintered composites of WC–WB–W2B were prepared from B4C–W–WC powders using a reactive energization hot-pressing technique that initiated a solid state reaction between B4C and W. Below a WC mole fraction of 0.769 in the starting powder, WB and WC were formed according to the reaction B4C+5W+xWC=WB+(1+x)WC, while WB, W2B, and WC were produced above a mole fraction of 0.854. Densely sintered bodies were not obtained for pure WC. Composites of WC–WB–W2B obtained at WC mole fractions between 0.854 and 0.956 were fully consolidated, having high Young’s modulus and Vickers hardness values, and a fracture toughness which were comparable to those of WC.

Journal

  • MATERIALS TRANSACTIONS

    MATERIALS TRANSACTIONS 43 (5), 1197-1201, 2002

    The Japan Institute of Metals and Materials

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