Properties and Characterization of Perovskite Related Oxides for Rapid CO2 Solidification

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Abstract

Perovskite related oxides such as (Ba, Ca)(Fe, Co)O3-δ, (Sr, Ca)(Fe, Co)O3-δ and (Ba, Ca)(Fe, Mg)O3-δ have been developed as safety materials for quick solidification of CO2 at high temperatures. The CO2 solidification properties and microstructures were investigated. Perovskite oxides (ABO3) become active for CO2 accommodation due to the lattice distortion produced by mixing different alkaline earth ions in site A and the mixed valence states by substitution of Fe ions by Cc and Mg ions in site B. The mechanism of rapid CO2 accommodation was taken into consideration.

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