Fluorescence Probing of Self-Assembled Monolayer with Terphenyl-Derivatized Disulfides

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著者

    • Fukushima Hitoshi [他] Fukushima Hitoshi
    • Joint Research Center for Harmonized Molecular Materials (JACHMM), Japan Chemical Innovation Institute (JCII), c/o Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8562, Japan
    • Tamaki Takashi
    • Institute for Materials and Chemical Process (IMCP), National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8562, Japan

抄録

The formation processes of and molecular ordering in self-assembled monolayers were investigated by fluorescence probing with $p$-terphenyl chromophores binding to disulfides at the $o$- or $p$-positions. In mixtures with dodecanethiol, the derivatized disulfides formed ordered monolayers. As compared with the broad monotonic fluorescence spectra in solutions, their emission bands were split into distinct peaks upon chemisorption on gold substrates due to intermolecular interactions between adjacent terphenyl groups. Their emission peak positions were interpreted in terms of the exciton coupling of various dimeric terphenyl configurations in the monolayers depending on the $o$- and $p$-isomeric structures.

収録刊行物

  • Japanese journal of applied physics. Pt. 1, Regular papers & short notes

    Japanese journal of applied physics. Pt. 1, Regular papers & short notes 42(11), 7067-7070, 2003-11-15

    公益社団法人 応用物理学会

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各種コード

  • NII論文ID(NAID)
    10012564721
  • NII書誌ID(NCID)
    AA10457675
  • 本文言語コード
    EN
  • 資料種別
    ART
  • 雑誌種別
    大学紀要
  • ISSN
    0021-4922
  • NDL 記事登録ID
    6753036
  • NDL 雑誌分類
    ZM35(科学技術--物理学)
  • NDL 請求記号
    Z53-A375
  • データ提供元
    CJP書誌  NDL  J-STAGE  JSAP 
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