超臨界流体クロマトグラフィーによるオリゴマーの重合度分別と高分子科学への応用 Separation of Individual Oligomer Homologs by Supercritical Fluid Chromatography and Applications of the Oligomers to Polymer Science

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Recent progress in supercritical fluid chromatography (SFC) of oligomers and application of the individual oligomer homologs to polymer science are described. First, the feasibility of using a monolithic silica-rod column for the SFC separation of Silicone-OV17, Triton-X100, and isotactic poly(methyl methacrylate) (PMMA) was examined. The monolithic silica-rod column showed higher separation efficiency in the SFC separation of oligomer homologs than conventional columns packed with silica particles (5μm).<br>Second, SFC was applied to the analysis of polyprenols extracted from bark, oot, leaf, and seed coat of a rubber-producing plant, <i>Eucommia ulmoides oliver</i>. The analysis clearly showed that the polyprenols from bark consists entirely of poly-<i>cis</i> homologs while those from root and seed coat consist of poly-<i>cis</i> and poly-<i>trans</i> homologs. Both SFC and matrix-assisted laser-desorption ionization mass spectrometry analyses of long-chain polyprenols from the leaves showed good resolution of poly-<i>trans</i> homologs up to 100mer. Third, applications of uniform isotactic and syndiotactic PMMAs obtained by SFC fractionation to the study of molecular weight dependence of diffusion coefficients and to the study of their stereocomplex formation are briefly mentioned.

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  • 日本ゴム協會誌

    日本ゴム協會誌 77(8), 278-281, 2004-08-15

    THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN

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各種コード

  • NII論文ID(NAID)
    10012803300
  • NII書誌ID(NCID)
    AN00189720
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    0029022X
  • NDL 記事登録ID
    7066263
  • NDL 雑誌分類
    ZP17(科学技術--化学・化学工業--高分子化学・高分子化学工業--ゴム・プラスチックス)
  • NDL 請求記号
    Z17-125
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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