超臨界二酸化炭素を媒体とする高分子合成 Polymerizations in Supercritical Carbon Dioxide

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著者

    • 寺境 光俊 JIKEI Mitsutoshi
    • 秋田大学工学資源学部環境物質工学科 Department of Material-process Engineering & Applied Chemistry for Environments, Akita University

抄録

Supercritical carbon dioxide deserves much attention as a sustainable solvent, potentially alternative to volatile organic solvents. It has been reported that numerous polymerizations can be carried out in supercritical carbon dioxide, despite of the limited solublity of polymeric materials. The article reviews the polymerizations in supercritical carbon dioxide which are classified into three categories: 1) chain-growth polymerizations; 2) step-growth polymerizations; 3) copolymerizations with carbon dioxide in supercritical carbon dioxide. It turned out that many radical polymerizations can be carried out in supercritical carbon dioxide with or without surfactants. Melt-polycondensations are also applicable in supercritical carbon dioxide. Carbon dioxide plays a role not only as a solvent but also as a reactive monomer in some polymerization reactions.

収録刊行物

  • 日本ゴム協會誌

    日本ゴム協會誌 77(8), 287-292, 2004-08-15

    THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN

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各種コード

  • NII論文ID(NAID)
    10012803343
  • NII書誌ID(NCID)
    AN00189720
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    0029022X
  • NDL 記事登録ID
    7066283
  • NDL 雑誌分類
    ZP17(科学技術--化学・化学工業--高分子化学・高分子化学工業--ゴム・プラスチックス)
  • NDL 請求記号
    Z17-125
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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