Hydrogen-bonded Macrocluster Formation of Ethylene Glycol on Silica Surfaces in Ethylene Glycol-Cyclohexane Binary Liquids

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著者

    • KURIHARA Kazue
    • Institute for Multidisciplinary Research for Advanced Materials, Tohoku University
    • NAKAGAWA Yasuhiro
    • Institute for Multidisciplinary Research for Advanced Materials, Tohoku University
    • MIZUKAMI Masashi
    • Institute for Multidisciplinary Research for Advanced Materials, Tohoku University

抄録

Adsorption of ethylene glycol on silica surfaces was investigated in cyclohexane. A long-range attraction appeared between the silica surfaces in the presence of ethylene glycol (>0.0005 mol%). ATR-FTIR spectra exhibited an absorption band at 3600–3000 cm<SUP>−1</SUP>, ascribed to the hydrogen-bonded hydroxyl groups. The results demonstrated that ethylene glycol adsorbed on the silica surfaces in a thick layer of several tens nm where it formed hydrogen-bonded molecular macroclusters.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(1), 84-85, 2003-01-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012813419
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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