Synthesis, Structure, and Preliminary Magnetic Studies of a Cluster Polymer with a Hexacopper(II) Barrel Portion

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The synthesis and characterization of a new cluster polymer with a sodium centered hexacopper(II) barrel portion, <I>catena</I>-[Na⊂Cu<SUB>2</SUB>{Cu(hpro)<SUB>2</SUB>}<SUB>4</SUB>(ClO<SUB>4</SUB>)<SUB>4</SUB>](ClO<SUB>4</SUB>)·4H<SUB>2</SUB>O (hpro = 4-hydroxy-<FONT SIZE="-2">L</FONT>-prolinato) are described. The central sodium ion in the barrel portion is surrounded by eight carboxylate oxygen atoms from hpro ligands, which link the central metal to the copper atoms of four [Cu(hpro)<SUB>2</SUB>] units. These units are in turn connected to two further apical Cu<SUP>II</SUP> centers. The central alkali ion is therefore octahedrally surrounded by six copper atoms. The hydroxyl oxygen atoms of two hpro groups are coordinated to the axial copper atoms of two neighboring barrel portions, so that a chain complex forms. Magnetic studies indicate weak ferromagnetic coupling between copper(II) ions within the complex leading to a high spin multiplicity in the ground state.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(2), 202-203, 2003-02-05

    The Chemical Society of Japan

参考文献:  25件中 1-25件 を表示

  • <no title>

    ANDRUH M.

    J.Am.Chem.Soc. 115, 1822, 1993

    被引用文献8件

  • <no title>

    SANZ J. L.

    Inorg. Chem. 35, 7384, 1996

    被引用文献6件

  • <no title>

    COSTES J. P.

    Inorg. Chem. 36, 4284, 1997

    被引用文献2件

  • <no title>

    KAHN M. L.

    Inorg. Chem. 38, 3692, 1999

    被引用文献2件

  • <no title>

    YANG Y.-Y.

    J. Chem. Soc., Dalton Trans. 2005, 1999

    被引用文献1件

  • <no title>

    MAO J.-G.

    J. Chem. Crystallogr. 6, 475, 1998

    被引用文献1件

  • <no title>

    CUI Y.

    J. Chem. Soc., Dalton Trans. 2955, 1998

    被引用文献1件

  • <no title>

    DECURTINS S.

    Inorg.Chem. 37, 2443, 1998

    被引用文献6件

  • <no title>

    CUI Y.

    Chem. Lett. 281, 1999

    被引用文献2件

  • <no title>

    ZHONG Z. J.

    J. Am. Chem. Soc. 122, 2952, 2000

    被引用文献2件

  • <no title>

    KIDO T.

    J. Chem. Soc., Chem. Commun. 2113, 2000

    被引用文献1件

  • <no title>

    NIHEI M.

    Chem. Lett. 1016, 2002

    被引用文献3件

  • <no title>

    IGARASHI S.

    Chem. Lett. 1265, 1999

    被引用文献1件

  • <no title>

    IGARASHI S.

    Inorg. Chem. 39, 2509, 2000

    被引用文献2件

  • <no title>

    VAN VLECK J. H.

    The Theory of Electric and Magnetic Susceptibilities, 1932

    被引用文献9件

  • <no title>

    KAMBE K.

    J. Phys. Soc. Jpn. 5, 48, 1950

    被引用文献12件

  • <no title>

    RAMADE I.

    Inorg. Chem. 36, 930, 1997

    DOI 被引用文献10件

  • <no title>

    CUI Y.

    Inorg. Chim. Acta 293, 129, 1999

    被引用文献1件

  • <no title>

    CUI Y.

    Inorg. Chem. 39, 4165, 2000

    被引用文献1件

  • <no title>

    YUKAWA Y.

    J. Chem. Soc., Chem. Commun. 711, 1997

    被引用文献2件

  • <no title>

    BLAKE A. J.

    J. Chem. Soc., Chem. Commun. 2363, 1994

    被引用文献1件

  • <no title>

    DEARDEN A. L.

    Angew. Chem. Int. Ed. 40, 152, 2001

    被引用文献1件

  • <no title>

    HULSBERGEN F. B.

    J. Chem. Soc., Dalton Trans. 539, 1983

    被引用文献1件

  • <no title>

    TERCERO J.

    Inorg. Chem. 40, 3077, 2001

    被引用文献1件

  • <no title>

    AROMI G.

    Angew. Chem., Int. Ed. 41, 1168, 2002

    被引用文献1件

各種コード

  • NII論文ID(NAID)
    10012814306
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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