Synthesis and Reactions of the First Allenyl Azo Compounds

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Several propargylhydrazines were prepared and then oxidized by manganese dioxide to generate short-lived 1,1-diazenes, which produced novel allenyl azo compounds (<B>8</B>) through [2,3] sigmatropic rearrangement. Isomerization of <B>8</B> or nucleophilic addition to the title compounds lead to hydrazones as well as pyrazole derivatives.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(4), 360-361, 2003-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012815570
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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