Zinc Tetrafluoroborate-Catalyzed Efficient Conversion of Aldehydes to Geminal Diacetates and Cyanoacetates

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著者

    • RANU Brindaban C.
    • Department of Organic Chemistry, Indian Association for the Cultivation of Science
    • DUTTA Jyotirmoy
    • Department of Organic Chemistry, Indian Association for the Cultivation of Science
    • DAS Arijit
    • Department of Organic Chemistry, Indian Association for the Cultivation of Science

抄録

A trace of an aqueous solution of zinc tetrafluoroborate was demonstrated to catalyze the conversion of an aldehyde to its 1,1-diacetate by acetic anhydride without any solvent. A similar reaction of an aldehyde with a mixture of potassium cyanide and acetic anhydride in methylene chloride was also catalyzed by Zn(BF<SUB>4</SUB>)<SUB>2</SUB> to provide the corresponding geminal cyanoacetate.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(4), 366-367, 2003-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012815622
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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