Anomalous Temperature Dependence of the Magnetic Susceptibility of a Ni(II) Cyclam Complex with Iodide

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著者

    • YAMAUCHI Jun
    • Graduate School of Human and Environmental Studies, Kyoto University
    • SAKAI Naoko
    • Graduate School of Human and Environmental Studies, Kyoto University

抄録

Magnetic susceptibility was studied on a Ni(II) cyclam complex with iodide, which exhibited an anomalous temperature variation. A diamagnetic spin state at room temperature made a transition into a paramagnetic state below ca. 50 K, and the magnetic susceptibility increased continuously toward a liquid helium temperature. An ESR observation was in good agreement with this magnetic behavior. This finding is unusual in spin crossover phenomena in transition metal ions.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(4), 368-369, 2003-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012815647
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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