Synthesis and Facile Rearrangement of 10,10-Dicarbonyl-substituted [4.3.1]Propellane Derivatives

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  • Yoshito Tobe
    Department of Chemistry, Faculty of Engineering Science, Osaka UniversityToyonaka, Osaka
  • Takuji Kusumoto
    Department of Chemistry, Faculty of Engineering Science, Osaka UniversityToyonaka, Osaka
  • Shiho Minakata
    Department of Chemistry, Faculty of Engineering Science, Osaka UniversityToyonaka, Osaka
  • Rui Umeda
    Department of Chemistry, Faculty of Engineering Science, Osaka UniversityToyonaka, Osaka
  • Motohiro Sonoda
    Department of Chemistry, Faculty of Engineering Science, Osaka UniversityToyonaka, Osaka
  • Koichiro Naemura
    Department of Chemistry, Faculty of Engineering Science, Osaka UniversityToyonaka, Osaka

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<jats:title>Abstract</jats:title> <jats:p>While an attempt to prepare 10,10-diformyl[4.3.1]propella-1,4-diene was not successful owing to its facial skeletal rearrangement, the corresponding diacetyl derivative was isolated, which would serve as a useful precursor of carbene sources.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 32 (4), 398-399, 2003-03-31

    Oxford University Press (OUP)

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