Non-aggregated Intercalation of Dicationic Tetraphenylporphyrinatoantimony(V) Complexes into Smectite Clay Layers

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  • Tsutomu Shiragami
    Department of Applied Chemistry, Faculty of Engineering, Miyazaki UniversityGakuen-Kibanadai, Miyazaki
  • Keiko Nabeshima
    Department of Applied Chemistry, Faculty of Engineering, Miyazaki UniversityGakuen-Kibanadai, Miyazaki
  • Jin Matsumoto
    Department of Applied Chemistry, Faculty of Engineering, Miyazaki UniversityGakuen-Kibanadai, Miyazaki
  • Masahide Yasuda
    Department of Applied Chemistry, Faculty of Engineering, Miyazaki UniversityGakuen-Kibanadai, Miyazaki
  • Haruo Inoue
    CREST, JST (Japan Science and Technology)

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<jats:title>Abstract</jats:title> <jats:p>Adsorption and intercalation of +2 charged cationic [3-(trimethylammonio)propoxo(methoxo)(tetraphenylporphyrinato)antimony(V)]2+ (1a) into an artificially synthesized smectite clay were studied. The red shift of Soret band in UV-spectra for 1a in an aqueous colloidal clay solution and analyses of X-ray diffraction of the obtained complex between 1a and the clay indicate the intercalation of 1a into the clay interlayer. Ammonium cationic part on an axial ligand led to the effective non-aggregated intercalation of 1a into the clay.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 32 (6), 484-485, 2003-05-06

    Oxford University Press (OUP)

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