Non-aggregated Intercalation of Dicationic Tetraphenylporphyrinatoantimony(V) Complexes into Smectite Clay Layers

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著者

    • SHIRAGAMI Tsutomu
    • Department of Applied Chemistry, Faculty of Engineering, Miyazaki University
    • NABESHIMA Keiko
    • Department of Applied Chemistry, Faculty of Engineering, Miyazaki University
    • MATSUMOTO Jin
    • Department of Applied Chemistry, Faculty of Engineering, Miyazaki University
    • YASUDA Masahide
    • Department of Applied Chemistry, Faculty of Engineering, Miyazaki University

抄録

Adsorption and intercalation of +2 charged cationic [3-(trimethylammonio)propoxo(methoxo)(tetraphenylporphyrinato)antimony(V)]<SUP>2+</SUP> (<B>1a</B>) into an artificially synthesized smectite clay were studied. The red shift of Soret band in UV-spectra for <B>1a</B> in an aqueous colloidal clay solution and analyses of X-ray diffraction of the obtained complex between <B>1a</B> and the clay indicate the intercalation of <B>1a</B> into the clay interlayer. Ammonium cationic part on an axial ligand led to the effective non-aggregated intercalation of <B>1a</B> into the clay.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(6), 484-485, 2003-06-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012816573
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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