Raman Spectra, Crystal Polymorphism, and Structure of a Prototype Ionic-liquid [bmim]Cl

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著者

    • HAYASHI Satoshi
    • Department of Chemistry, School of Science, The University of Tokyo
    • OZAWA Ryosuke
    • Department of Chemistry, School of Science, The University of Tokyo

抄録

A prototype ionic-liquid [bmim]Cl shows crystal polymorphism, having two crystal forms, Crystal (1) and Crystal (2), characterized by distinct X-ray powder patterns and Raman spectra. Two sets of characteristic Raman bands of Crystals (1) and (2), which are mutually exclusive with each other, do coexist in the spectrum of liquid [bmim]Cl. It seems that two distinct structures of the [bmim]<SUP>+</SUP> ion, one corresponding to that in Crystal (1) and the other to that in Crystal (2), exist simultaneously in the ionic liquid state.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(6), 498-499, 2003-06-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012816675
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  CJP引用  J-STAGE 
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