Amination of Arenes with <i>N</i>,<i>N</i>-Dimethyl-2-imidazolidinone <i>O</i>-Methoxyacetyloxime

  • Nicolas Baldovini
    Department of Chemistry, Graduate School of Science, The University of Tokyo7-3-1 Hongo, Bunkyo-ku, Tokyo
  • Mitsuru Kitamura
    Department of Chemistry, Graduate School of Science, The University of Tokyo7-3-1 Hongo, Bunkyo-ku, Tokyo
  • Koichi Narasaka
    Department of Chemistry, Graduate School of Science, The University of Tokyo7-3-1 Hongo, Bunkyo-ku, Tokyo

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Treatment of nucleophilic arenes with N,N-dimethyl-2-imidazolidinone O-methoxyacetyloxime and SnCl4 produced the corresponding N-arylimines, which were converted to anilines by hydrolysis with CsOH and to N-methylanilines by LiAlH4 reduction.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 32 (6), 548-549, 2003-05-27

    Oxford University Press (OUP)

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