Eco-friendly and Highly Chemoselective 1, 3-Oxathio- and 1, 3-Dithioacetalization of Aldehydes Using Ionic Liquids

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著者

    • YADAV J. S.
    • Division of Organic Chemistry, Indian Institute of Chemical Technology
    • REDDY B. V. S.
    • Division of Organic Chemistry, Indian Institute of Chemical Technology
    • KONDAJI G.
    • Division of Organic Chemistry, Indian Institute of Chemical Technology

抄録

Room temperature ionic liquids have been employed for the first time as novel and recyclable reaction media for the chemoselective conversion of aldehydes into their corresponding 1,3-oxathio- and dithioacetal derivatives in excellent yields under mild and neutral conditions. A wide range of functional and protecting groups such as TBDMS, PMB, THP, MOM, benzyl, propargyl ethers, acetonides, carbamates and esters are survived under these reaction conditions. The recovered activated ionic liquids can be recycled for four to five subsequent runs with consistency in activity.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(8), 672-673, 2003-08-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012817966
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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