Regioselective Radical Cyclization by Electrochemical Reduction Using an Arene Mediator. Environmentally Benign Method

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著者

    • KURONO Nobuhito
    • Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University
    • HONDA Eiichi
    • Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University
    • KOMATSU Fumikazu
    • Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University
    • ORITO Kazuhiko
    • Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University
    • TOKUDA Masao
    • Division of Molecular Chemistry, Graduate School of Engineering, Hokkaido University

抄録

Electrochemical reduction of 2-(but-3-enyl)-1-haloarenes in the presence of phenanthrene as a mediator generated the corresponding aryl radicals and gave cyclized products in good yields. Higher regio- and stereoselectivities than those of usual radical cyclization using AIBN-TBTH were achieved.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(8), 720-721, 2003-08-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012818338
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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