A Well Characterized Example of Conversion of Molecular Configuration Depending on the Existence of Intermolecular Interactions

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  • Qin-Yu Zhu
    Department of Chemistry & Chemical Engineering, Suzhou UniversitySuZhou 215006, P. R . China
  • Yong Zhang
    Department of Chemistry & Chemical Engineering, Suzhou UniversitySuZhou 215006, P. R . China
  • Jie Dai
    Department of Chemistry & Chemical Engineering, Suzhou UniversitySuZhou 215006, P. R . China
  • Guo-Qing Bian
    Department of Chemistry & Chemical Engineering, Suzhou UniversitySuZhou 215006, P. R . China
  • Ding-Xian Jia
    Department of Chemistry & Chemical Engineering, Suzhou UniversitySuZhou 215006, P. R . China
  • Jia-Sheng Zhang
    Department of Chemistry & Chemical Engineering, Suzhou UniversitySuZhou 215006, P. R . China
  • Lin Guo
    Department of Chemistry & Chemical Engineering, Suzhou UniversitySuZhou 215006, P. R . China

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Abstract

<jats:title>Abstract</jats:title> <jats:p>A new complex [Ag(L)2]ClO4·2CH2Cl2 (1) (L = 4′, 5′-diaza-9′-(4,5-dimethylthio-1,3-dithiole-2-ylidene)fluorene) was synthesized. It was confirmed by 1H NMR and X-ray structure determination that when the molecules crystallize out from solution, a conversion of molecular configuration occurs because of the strong intermolecular interactions.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 32 (8), 762-763, 2003-07-21

    Oxford University Press (OUP)

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