Highly Active, Thermally Robust V-based New Olefin Polymerization Catalyst System

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A new ethylene polymerization catalyst system containing a phenoxy-imine ligated V complex and a MgCl<SUB>2</SUB>-based compound has been discovered. Unlike ordinary V-based catalysts, the system exhibits higher activities at elevated temperatures, and the activity reached a very high value of 65100 kg-PE/mol-cat/h at 75 °C, representing the first example of a highly active, thermally robust V-based ethylene polymerization catalyst system.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(8), 766-767, 2003-08-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012818756
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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