A Strongly Antiferromagnetically Coupled Dinickel (II) Center Bridged by One Azido and One Alkoxo

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著者

    • FUJII Mie
    • Chemical Laboratory, Faculty of Education, Okayama University
    • GOTO Shoko
    • Chemical Laboratory, Faculty of Education, Okayama University
    • NAKAO Yasuo
    • Chemical Laboratory, Faculty of Education, Okayama University
    • SATO Tomohiko
    • Department of Chemistry, Faculty of Science, Kanagawa University
    • MORI Wasuke
    • Department of Chemistry, Faculty of Science, Kanagawa University

抄録

The dinuclear nickel(II) complexes [Ni<SUB>2</SUB>(L-Et)(μ-1,3-N<SUB>3</SUB>)(N<SUB>3</SUB>)(H<SUB>2</SUB>O)]·[Ni<SUB>2</SUB>(L-Et)(μ-1,3-N<SUB>3</SUB>)(N<SUB>3</SUB>)(CH<SUB>3</SUB>OH)](NO<SUB>3</SUB>)<SUB>2</SUB>·H<SUB>2</SUB>O, (<B>1</B>) and [Ni<SUB>2</SUB>(L-Et)(μ-1,3-N<SUB>3</SUB>)(N<SUB>3</SUB>)(H<SUB>2</SUB>O)]NO<SUB>3</SUB>·H<SUB>2</SUB>O, (<B>1</B>′) (HL-Et = <I>N</I>,<I>N</I>,<I>N</I>′,<I>N</I>′-tetrakis[(1-ethyl-2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane) bridged by one alkoxo of L-Et<SUP>−</SUP> and one azido were prepared and the crystal structure of <B>1</B> was determined by X-ray crystallography. Magnetic susceptibility measurements for <B>1</B>′ from liquid helium temperature to room temperature showed an antiferromagnetically strong interaction (2<I>J</I> = −187 cm<SUP>−1</SUP>, <I>H</I> = −2<I>JS</I><SUB>1</SUB>·<I>S</I><SUB>2</SUB>).

収録刊行物

  • Chemistry letters

    Chemistry letters 32(9), 868-869, 2003-09-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012819650
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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