Synthesis and Properties of Carbazole-Terephthalate Cyclophane

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著者

    • TANI Keita
    • Division of Natural Science, Osaka Kyoiku University
    • TOGO Eiichi
    • Division of Natural Science, Osaka Kyoiku University
    • TOHDA Yasuo
    • Division of Natural Science, Osaka Kyoiku University
    • OHKITA Hideo
    • Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University
    • ITO Shinzaburo
    • Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University
    • YAMAMOTO Masahide
    • Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University

抄録

As a first example of carbazole–acceptor cyclophane, carbazole–terephthalate cyclophane <B>1a</B> was prepared. The structure of <B>1a</B> was characterized by <SUP>1</SUP>H NMR and X-ray analysis. Absorption spectrum of <B>1a</B> showed the existence of transannular π–π electronic interaction and little charge transfer interaction. Fluorescence spectrum of <B>1a</B> in THF exhibited intramolecular exciplex emission around 525 nm.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(10), 910-911, 2003-10-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012819952
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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