A Cationic Diruthenium Amidinate, [(η^5-C_5Me_5)Ru(μ_2-i-PrN=C(Me)Ni-Pr)Ru(η^5-C_5Me_5)]^+, as an Efficient Catalyst for the Atom-Transfer Radical Reactions

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著者

    • MOTOYAMA Yukihiro
    • Institute for Materials Chemistry and Engineering, Graduate School of Engineering Sciences, Kyushu University
    • GONDO Mitsuru
    • Institute for Materials Chemistry and Engineering, Graduate School of Engineering Sciences, Kyushu University
    • MASUDA Satoshi
    • Institute for Materials Chemistry and Engineering, Graduate School of Engineering Sciences, Kyushu University
    • IWASHITA Yuya
    • Institute for Materials Chemistry and Engineering, Graduate School of Engineering Sciences, Kyushu University
    • NAGASHIMA Hideo
    • Institute for Materials Chemistry and Engineering, Graduate School of Engineering Sciences, Kyushu University

抄録

A cationic diruthenium amidinate, [(η<SUP>5</SUP>-C<SUB>5</SUB>Me<SUB>5</SUB>)Ru(μ<SUB>2</SUB>-<I>i</I>-PrN=C(Me)N<I>i</I>-Pr)Ru(η<SUP>5</SUP>-C<SUB>5</SUB>Me<SUB>5</SUB>)]<SUP>+</SUP>, is generated by treatment of (η<SUP>5</SUP>-C<SUB>5</SUB>Me<SUB>5</SUB>)Ru(μ<SUB>2</SUB>-<I>i</I>-PrN=C(Me)N<I>i</I>-Pr)Ru(Cl)(η<SUP>5</SUP>-C<SUB>5</SUB>Me<SUB>5</SUB>) (<B>3a</B>) with NaPF<SUB>6</SUB> or other metal salts of weakly coordinating anions, which is active towards catalytic atom transfer radical cyclization of <I>N</I>-allyl trichloroacetamides and related reactions.

収録刊行物

  • Chemistry letters

    Chemistry letters 33(4), 442-443, 2004-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012847281
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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