A Cationic Diruthenium Amidinate, [(η5-C5Me5)Ru(μ2-<i>i</i>-PrN=C(Me)N<i>i</i>-Pr)Ru(η5-C5Me5)]+, as an Efficient Catalyst for the Atom-Transfer Radical Reactions
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- Yukihiro Motoyama
- Institute for Materials Chemistry and Engineering, Graduate School of Engineering Sciences, Kyushu University
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- Mitsuru Gondo
- Institute for Materials Chemistry and Engineering, Graduate School of Engineering Sciences, Kyushu University
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- Satoshi Masuda
- Institute for Materials Chemistry and Engineering, Graduate School of Engineering Sciences, Kyushu University
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- Yuya Iwashita
- Institute for Materials Chemistry and Engineering, Graduate School of Engineering Sciences, Kyushu University
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- Hideo Nagashima
- Institute for Materials Chemistry and Engineering, Graduate School of Engineering Sciences, Kyushu University
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<jats:title>Abstract</jats:title> <jats:p>A cationic diruthenium amidinate, [(η5-C5Me5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(η5-C5Me5)]+, is generated by treatment of (η5-C5Me5)Ru(μ2-i-PrN=C(Me)Ni-Pr)Ru(Cl)(η5-C5Me5) (3a) with NaPF6 or other metal salts of weakly coordinating anions, which is active towards catalytic atom transfer radical cyclization of N-allyl trichloroacetamides and related reactions.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 33 (4), 442-443, 2004-03-20
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360002219110473472
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- NII論文ID
- 10012847281
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- NII書誌ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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