Unprecedented Pendant Group Exchange of a Porphyrinato Platinum(II) in Benzonitrile

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著者

    • ARAKI Naoko
    • Division of Natural Science and Ecological Awareness, Graduate School of Humanities and Sciences, Nara Women's University
    • OBATA Makoto
    • Division of Natural Science and Ecological Awareness, Graduate School of Humanities and Sciences, Nara Women's University
    • ICHIMURA Akio
    • Department of Chemistry, Graduate School of Science, Osaka City University
    • YANO Shigenobu
    • Division of Natural Science and Ecological Awareness, Graduate School of Humanities and Sciences, Nara Women's University

抄録

5-(4-cyanophenyl)-10,15,20-triphenylporphyrinato platinum(II) (<B>3</B>) and 5-(4-methoxycarbonylphenyl)-10,15,20-triphenylporphyrinato platinum(II) (<B>2</B>) were isolated from a reaction of 5-(4-methoxycarbonylphenyl)-10,15,20-triphenyl porphyrin (<B>1</B>) with K<SUB>2</SUB>[PtCl<SUB>4</SUB>] in benzonitrile. Seemingly, <B>3</B> was generated through the functional group substitution reaction of the phenyl group of tetraphenylporphyrin during platinum ion insertion into <B>1</B> and was characterized by <SUP>1</SUP>H NMR, mass spectroscopy, elemental analysis, and X-ray crystallography.

収録刊行物

  • Chemistry letters

    Chemistry letters 33(4), 450-451, 2004-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012847351
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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