Synthesis and Physical Nature of Fluorescent Photoaffinity Probe for the Bioorganic Studies on Tautomycin, a Protein Phosphatase Type 1 Selective Inhibitor

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Fluorescent photoaffinity probe, which possesses a dansyl amide functional group on the maleic moiety of tautomycin, was prepared in order to detect the trace amount of labeled peptides. The parent compound dramatically showed fluorescence quenching before the photoreaction due to the exciplex formation on the basis of the folded conformation. Several benzhydrol analogs, on the other hand, recovered the strong fluorescence; thus, this system could be employed for the photoaffinity labeling studies.

収録刊行物

  • Chemistry letters

    Chemistry letters 33(4), 452-453, 2004-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012847370
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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