酸性クエン酸水溶液からのCdTe薄膜電析 Electrodeposition of CdTe from Acidic Aqueous Solutions Containing Citric Acid

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Potentiostatic cathodic electrodeposition of CdTe compound on a gold-plated substrate was studied at 70<sup>º</sup>C using new acidic aqueous electrolytic baths (pH3.0) containing citric acid. The composition of the deposits was controlled by changing the deposition potential, which depended on the concentrations of Te(IV) and citrate. The stoichiometric CdTe layers obtained were polycrystalline, having a uniform surface morphology without pinholes. In the presence of citrate ions, the solubility of tetravalent tellurium species in the citrate bath at pH3.0 was more than 10mM, which was about one or two orders higher than that in conventional acidic sulfate baths. The increase in the solubility will be accounted for by a complexation between Te(IV) and citrate ions, which has not been reported so far. A set of linear sweep cathodic voltammograms for Te(IV)-citrate baths suggested the presence of the complex.<br>

収録刊行物

  • 表面技術 = The Journal of the Surface Finishing Society of Japan

    表面技術 = The Journal of the Surface Finishing Society of Japan 55(5), 360-365, 2004-05-01

    The Surface Finishing Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012931608
  • NII書誌ID(NCID)
    AN1005202X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    09151869
  • NDL 記事登録ID
    6965618
  • NDL 雑誌分類
    ZP41(科学技術--金属工学・鉱山工学)
  • NDL 請求記号
    Z17-291
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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