Intercalation of Mercaptocarboxylic Acid into Layered Double Hydroxide Accompanied with Oxidation of Mercapto Group

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Author(s)

    • NAKAYAMA Hirokazu
    • Department of Functional Molecular Chemistry, Kobe Pharmaceutical University
    • HIRAMI Souichiro
    • Department of Functional Molecular Chemistry, Kobe Pharmaceutical University
    • TSUHAKO Mitsutomo
    • Department of Functional Molecular Chemistry, Kobe Pharmaceutical University

Abstract

The intercalation of mercaptocarboxylic acids into magnesium–aluminum layered double hydroxide (LDH) was accompanied with the oxidation of mercapto groups in aqueous solution as evidenced by <SUP>13</SUP>C solid-state NMR and Raman scattering measurements. The layers of LDH were bridged by two carboxylic groups of the corresponding disulfide, which was formed by the oxidation of mercaptocarboxylic acids.

Journal

  • Chemistry Letters

    Chemistry Letters 33(6), 712-713, 2004-06-05

    The Chemical Society of Japan

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Codes

  • NII Article ID (NAID)
    10013105808
  • NII NACSIS-CAT ID (NCID)
    AA00603318
  • Text Lang
    ENG
  • Article Type
    Journal Article
  • ISSN
    03667022
  • Data Source
    CJP  CJPref  J-STAGE 
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