Valence Electron Rules for Three- and Four-membered Atomic Rings : High-row Representative Elements

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Valence electron rules are proposed for the stability and instability of three- and four-membered atomic rings of high-row representative elements in the singlet states. Regular polygons with 4<I>N</I> + 2 and 8<I>N</I> + 6 valence electrons are the ground states of three- and four-membered rings, respectively. The rules are not necessarily applicable out of the range of the number of valence electrons (<I>N</I><SUB>ve</SUB>): 4<I>m</I> ≤ <I>N</I><SUB>ve</SUB> ≤ 6<I>m</I> for the groups 14–16 and 3<I>m</I> + [1 − (−1)<I><SUP>m</SUP></I>]/2 ≤ <I>N</I><SUB>ve</SUB> ≤ 6<I>m</I> for the group 13 where <I>m</I> is the number of the ring members.

収録刊行物

  • Chemistry letters

    Chemistry letters 33(7), 934-935, 2004-07-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10013285432
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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