Highly Efficient Production of Synthesis Gas by Catalytic Gasification of Biomass at Low Reaction Temperature.
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- Tomishige Keiichi
- Institute of Materials Science, University of Tsukuba
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- Asadullah Mohammad
- Institute of Materials Science, University of Tsukuba
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- Ito Shin-Ichi
- Institute of Materials Science, University of Tsukuba
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- Kunimori Kimio
- Institute of Materials Science, University of Tsukuba
Bibliographic Information
- Other Title
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- バイオマスの低温接触ガス化による高効率合成ガス製造
- バイオマス ノ テイオン セッショク ガスカ ニ ヨル コウコウリツ ゴウセイ ガス セイゾウ
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Abstract
Conventional methods of biomass gasification to hydrogen and synthesis gas are carried out at high temperature. The purpose of this study is to develop a novel catalytic process for biomass gasification at low temperature (773–873 K) with high energy efficiency. A cellulose was used as the model compound of biomass, and the performance of our catalysts was compared with those of dolomite and non -catalyst in batch and continuous-feeding fluidized bed reactor. In reaction tests with various catalysts, Rh/CeO2 exhibited higher performance than other catalysts, but its deactivation was also observed during the reaction, caused by the sintering of the CeO2 support. A commercial steam-reforming catalyst also showed high activity, but its deactivation due to carbon deposition was observed. We also prepared Rh/CeO2/SiO2, which gave higher C-conversion to gas and was more stable than Rh/CeO2. In comparison with conventional methods (dolomite, non-catalyst, Ni catalyst), it was found that the gasification using Rh/CeO2/SiO2 catalyst can give a higher yield of synthesis gas at much lower temperature and with higher stability.
Journal
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- KAGAKU KOGAKU RONBUNSHU
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KAGAKU KOGAKU RONBUNSHU 28 (6), 666-672, 2002
The Society of Chemical Engineers, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390282679485169920
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- NII Article ID
- 10013409744
- 10014605163
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- NII Book ID
- AN00037234
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- COI
- 1:CAS:528:DC%2BD38XptFCms7Y%3D
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- ISSN
- 13499203
- 0386216X
- http://id.crossref.org/issn/0386216X
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- NDL BIB ID
- 6362459
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed