Simultaneous Kinetic-Spectrophotometric Determination of Hydrazine and Acetylhydrazine in Micellar Media Using the H-Point Standard Addition Method

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  • AFKHAMI Abbas
    Department of Chemistry, Faculty of Sciences, Bu-Ali Sina University
  • ZAREI Ali Reza
    Department of Chemistry, Faculty of Sciences, Bu-Ali Sina University

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抄録

The H-point standard addition method (HPSAM), based on a spectrophotometric measurement for the simultaneous determination of hydrazine and acetylhydrazine, is described. This method is based on the difference between the rates of their reactions with N,N-dimethylaminobenzaldehyde (DAB) in the presence of sodium dodecyl sulfate (SDS) in acidic media. The results showed that hydrazine and acetylhydrazine could be determined simultaneously in the range of 0.020 - 0.70 and 0.20 - 5.0 mg L-1, respectively. Under the working conditions, the proposed method was successfully applied to the simultaneous determination of hydrazine and acetylhydrazine in several synthetic mixtures and plasma and water samples.

収録刊行物

  • Analytical Sciences

    Analytical Sciences 20 (8), 1199-1203, 2004

    社団法人 日本分析化学会

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