Construction of I-Xe and 40Ar-39Ar dating system using a modified VG3600 noble gas mass spectrometer and the first I-Xe data obtained in Japan

  • EBISAWA Noriko
    Laboratory for Earthquake Chemistry, Graduate School of Science, University of Tokyo
  • SUMINO Hirochika
    Laboratory for Earthquake Chemistry, Graduate School of Science, University of Tokyo
  • OKAZAKI Ryuji
    Laboratory for Earthquake Chemistry, Graduate School of Science, University of Tokyo
  • TAKIGAMI Yutaka
    Kanto Gakuen University
  • HIRANO Naoto
    Earthquake Research Institute, University of Tokyo
  • NAGAO Keisuke
    Laboratory for Earthquake Chemistry, Graduate School of Science, University of Tokyo
  • KANEOKA Ichiro
    Earthquake Research Institute, University of Tokyo

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タイトル別名
  • Construction of I-Xe and 40Ar-39Ar Dating System Using a Modified VG3600 Mass Spectrometer and the First I-Xe Data Obtained in Japan

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Improvements in ion collectors of the VG3600 mass spectrometer used for 40Ar-39Ar dating in the Radioisotope Center, University of Tokyo, have been performed. We also constructed a new compact vacuum line for extraction and purification of noble gases, and connected it to the mass spectrometer. The new noble gas mass spectrometry system enables us to measure all noble gases (He, Ne, Ar, Kr, and Xe) at low detection limits corresponding to 2×10-15 cm3 STP or 5×103 atoms of Kr and Xe. A newly designed W-coil furnace effectively heats small samples (1-100 mg) in a Mo-crucible with condition of low blank levels (10-10 and 10-15 cm3 STP for Ar and Xe). Smaller sample sizes required for 40Ar-39Ar dating have reduced activity levels. The system was preliminarily applied to I-Xe dating of neutron irradiated meteorites, Bjurböle, Allende and Yamato-74191, and discovered a late formation age of Yamato-74191 (26 Ma after Bjurböle) compared with the Allende meteorite.

収録刊行物

  • 質量分析

    質量分析 52 (4), 219-229, 2004

    一般社団法人 日本質量分析学会

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