Synthesis, Structure, and Electron-Donating Ability of 2, 2' : 6', 2"-Dioxatriphenylamine and Its Sulfur Analogue

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著者

    • KURATSU Masato
    • Department of Chemistry, Graduate School of Science, Osaka City University
    • KOZAKI Masatoshi
    • Department of Chemistry, Graduate School of Science, Osaka City University
    • OKADA Keiji
    • Department of Chemistry, Graduate School of Science, Osaka City University

抄録

2,2′:6′,2″-Dioxa- and dithia-triphenylamines <B>4a</B> and <B>4b</B> were prepared. Both compounds had a <I>C</I><SUB>2</SUB>-like structure. The sulfur compound <B>4b</B> had a more twisted structure than <B>4a</B>; the dihedral angle between two edge phenyl rings was 43° for <B>4a</B>, and 62° for <B>4b</B>. The oxygen compound <B>4a</B> had a reversible oxidation wave at +0.81 V vs SCE, whereas <B>4b</B> had an irreversible peak at +1.14 V.

収録刊行物

  • Chemistry letters

    Chemistry letters 33(9), 1174-1175, 2004-09-05

    公益社団法人 日本化学会

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各種コード

  • NII論文ID(NAID)
    10013527859
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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