Determination of the Field Strengths of Weak Neutral Ligands Having Oxygen as Coordination Atom

• Akito Hoshino

  Division of Biomolecular Science, Graduate School of Science, Toho University

• Mikio Nakamura

  Department of Chemistry, School of Medicine, Toho University

抄録

Weakness of various neutral ligands having oxygen as coordination atom was ranked on the basis of the pyrrole proton chemical shifts of planar [Fe(TPP)L2]+. Furthermore, weakness of the ligands, which is difficult to determine from the NMR data of planar [Fe(TPP)L2]+, was successfully differentiated by the use of highly ruffled [Fe(TiPrP)L2]+. Among the 10 ligands examined, THF turned out to be the weakest ligand.

収録刊行物

• Chemistry Letters

  Chemistry Letters 33 (10), 1234-1235, 2004-08-28

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219110382464
• NII論文ID: 10013657825
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2004.1234
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/33/10/1234/55584595/cl.2004.1234.pdf
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