The Reaction of Butatrienolates with Aldehydes for the Syntheses of α-Vinylidene Acylsilanes

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著者

    • SHIBATA Takanori
    • Department of Chemistry, School of Science and Engineering, Waseda University
    • TAKAMI Kyoko
    • Department of Chemistry, School of Science and Engineering, Waseda University
    • ARAI Yoshikazu
    • Department of Chemistry, School of Science and Engineering, Waseda University
    • TSUCHIKAMA Kyoji
    • Department of Chemistry, School of Science and Engineering, Waseda University
    • MAEKAWA Shunsuke
    • Department of Chemistry, School of Science and Engineering, Waseda University

抄録

Lithium butatrienolates were prepared in situ by the 1,4-elimination from 2-butynyl trimethylsilyl ethers along with a retro-Brook rearrangement. The addition reaction of the enolates with the aldehydes afforded β-hydroxy-α-vinylidene acylsilanes.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 77(10), 1937-1938, 2004-10-15

    公益社団法人 日本化学会

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各種コード

  • NII論文ID(NAID)
    10013738022
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • データ提供元
    CJP書誌  J-STAGE 
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