Photochemical Generation of Halo(silyl)silylene : Spectroscopic Observation and Reactivity

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著者

    • TANAKA Takashi
    • Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba
    • ICHINOHE Masaaki
    • Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba
    • SEKIGUCHI Akira
    • Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba

抄録

Dihalobis(tri-<I>tert</I>-butylsilyl)silanes (<I>t</I>-Bu<SUB>3</SUB>Si)<SUB>2</SUB>SiX<SUB>2</SUB> (<B>1a</B>: X = Cl, <B>1b</B>: X = Br) underwent photochemically α-elimination to produce halo(tri-<I>tert</I>-butylsilyl)silylenes, which were successively trapped by carbon tetrachloride, triethylsilane, and 3-hexyne. The halo(tri-<I>tert</I>-butylsily)silylenes were observed by UV–vis spectroscopy in a 3-methylpentane matrix at 77 K.

収録刊行物

  • Chemistry letters

    Chemistry letters 33(11), 1420-1421, 2004-11-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10013771549
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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