Evidence for Two Competing Mechanisms in Regeneration of 2-(2, 4-Dinitrobenzyl)pyridine from its Enamine Tautomer

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著者

    • KIRA Nobuhiro
    • Department of Applied Chemistry, Faculty of Engineering, Oita University
    • TAKAHASHI Toru
    • Department of Applied Chemistry, Faculty of Engineering, Oita University
    • OHGA Yasushi
    • Department of Applied Chemistry, Faculty of Engineering, Oita University
    • ASANO Tsutomu
    • Department of Applied Chemistry, Faculty of Engineering, Oita University

抄録

Kinetic effects of pressure on the title reaction were studied. The reaction was insensitive to a change in pressure at 0.1 MPa, however, it was accelerated by an increase in pressure at <I>P</I> > 100 MPa, showing the existence of two reaction routes with and without solvent participation. Viscosity-induced retardations observed in highly viscous media supported intervention of solvent molecules at high pressures.

収録刊行物

  • Chemistry letters

    Chemistry letters 33(11), 1444-1445, 2004-11-05

    公益社団法人 日本化学会

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各種コード

  • NII論文ID(NAID)
    10013771752
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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