1, 1-ジフェニルエチレン誘導体を用いたマルチファンクショナルSBRの合成 Synthesis of Multi-Functional SBR by Using 1, 1-Diphenylethylene Derivative

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著者

    • 平尾 明 HIRAO Akira
    • 東京工業大学大学院理工学研究科 有機・高分子物質専攻 Polymeric and Organic Materials Department, Graduate School of Science and Engineering, Tokyo Institute of Technology

抄録

Much attention has been paid to the end-functionalized solution styrene-butadiene rubber (S-SBR) for the purpose of improving the interaction between the polymer and silica filler. Recently, we have been developing a new one-step methodology based on living anionic polymerization and 1, 1-diphenylethylene chemistry for synthesizing well-defined functionalized SBR with dimethylamino groups at both chain ends. This one-step methodology involves living anionic copolymerization of styrene and butadiene by treating with functionalized initiator synthesized from two equivalent of dimethylamino-functionalized DPE with sec-BuLi. The resulting copolymers were characterized by GPC, SLS, NMR, titration, and polymer reactions to show the expected chain-end-functionalized structures. As an extention of this methodology, a more complex multi-functionalized SBR with three dimethylamino groups at both chain ends and in chain could be successfully synthesized by treating with functionalized initiator synthesized from three equivalent of the DPE with sec-BuLi.

収録刊行物

  • 日本ゴム協會誌

    日本ゴム協會誌 78(3), 91-97, 2005-03-15

    THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN

参考文献:  9件中 1-9件 を表示

  • <no title>

    INAGAKI K.

    Sumitomokagaku Gijyutusi 2004-I, 13, 2004

    被引用文献1件

  • <no title>

    FUJIMAKI T.

    Nippon Gomu Kyokaishi 71, 562, 1998

    被引用文献2件

  • <no title>

    HAYASHI M.

    Macromol. Chem. Phys. 202, 1717, 2001

    被引用文献2件

  • <no title>

    HSIEH H. L.

    "Anionic Polymerization: Principles and Practical Applications", 1996

    被引用文献3件

  • <no title>

    HIRAO A.

    Macromolecules 29, 3353, 1996

    被引用文献3件

  • <no title>

    QUIRK R. P.

    Brit. Polym. J. 47, 23, 1990

    被引用文献1件

  • <no title>

    SELA M.

    J. Am. Chem. Soc. 77, 1893, 1955

    被引用文献1件

  • <no title>

    QUIRK R. P.

    Macromol. Symp. 63, 259, 1992

    被引用文献1件

  • <no title>

    QUIRK R. P.

    Polym. Internat. 27, 1, 1992

    被引用文献1件

被引用文献:  2件中 1-2件 を表示

各種コード

  • NII論文ID(NAID)
    10013818601
  • NII書誌ID(NCID)
    AN00189720
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    0029022X
  • NDL 記事登録ID
    7279236
  • NDL 雑誌分類
    ZP17(科学技術--化学・化学工業--高分子化学・高分子化学工業--ゴム・プラスチックス)
  • NDL 請求記号
    Z17-125
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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