Influence of Mo and W on Morphology and Alloy Content of Crystallized Carbides in Multi-component White Cast Iron

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  • 多合金系白鋳鉄の晶出炭化物の形状とその組成に及ぼすモリブデン,タングステンの影響
  • タゴウキンケイ ハク チュウテツ ノ ショウシュツ タンカブツ ノ ケイジョウ ト ソノ ソセイ ニ オヨボス モリブデン タングステン ノ エイキョウ

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Abstract

  Multi-component white cast iron was developed for rolling mill rolls and is spreading widely. The morphology and alloy concentration of crystallized carbides were investigated by SEM, TEM and EDS analyses using three irons with typical chemical composition of Fe-2%C-5%Cr-5%V-Mo-W (mass%) system, and the influence of Mo and W on these irons was studied. The reaction of M2C + γ-Fe → M6C + MC + M7C3, which occurs by heat treatment, could be suppressed by increasing Mo content. It was found that there exists a linear relation between alloy content in each carbide and Mo ratio Mo/(Mo + W) of molten metal. In high W material, however, W contents of crystallized MC, M2C and transformed M6C crbides were saturated values.

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