Decomposition of Trichlorobenzene Isomers by Co-Grinding with CaO

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Two types of trichlorobenzene (TCB) isomers, 1,2,3- and 1,3,5-, were subjected to grinding in air with CaO in a planetary ball mill to investigate their decomposition phenomena. Results showed that TCB samples were decomposed by the co-grinding to form calcium chloride hydrate and amorphous carbon as the main products, with other minor compositions such as carbon dioxide and water. There was no significant difference in the decomposition phenomena between the two isomers. Radicals were generated during the decomposition process, predominantly due to the rupture of C–Cl bonds in the molecule. Supported by the simulation data, we concluded that dehydrochlorination during TCB decomposition process to form hydrochloride (HCl, further to CaOHCl) exhibited the lower possibility, suggesting dechlorination rather than dehydrochlorination as the plausible decomposition pathway.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 76(10), 1919-1925, 2003-10-15

    日本化学会

参考文献:  25件中 1-25件 を表示

  • <no title>

    ZHANG Q. W.

    Environ. Sci. Technol. 35, 4933, 2001

    被引用文献1件

  • <no title>

    ZHANG Q. W.

    Chemosphere 48, 787, 2002

    被引用文献1件

  • <no title>

    GAO G.

    Ind. Eng. Chem. Res. 38, 3218, 1999

    被引用文献1件

  • <no title>

    ROWLANDS S. A.

    Nature 367, 223, 1994

    被引用文献4件

  • <no title>

    SHINOHARA Y.

    J. Mol. Struct. : THEOCHEM 497, 1, 2000

    被引用文献1件

  • <no title>

    FRISCH M. J.

    Gaussian 98, 1998

    被引用文献106件

  • <no title>

    CHEN C. J.

    J. Phys. Chem. A 103, 9731, 1999

    被引用文献1件

  • <no title>

    STEWART J. J. P.

    J. Comput. Chem. 10, 209, 1989

    被引用文献66件

  • <no title>

    STEWART J. J. P.

    J. Comput. -Aided Mol. Des. 4, 1, 1990

    被引用文献9件

  • <no title>

    WAKAYAMA H.

    Carbon 37, 947, 1999

    被引用文献5件

  • <no title>

    ZHANG Q. W.

    Chem. Lett. 2001, 148, 2001

    被引用文献1件

  • <no title>

    IKOMA T.

    Bull. Chem. Soc. Jpn. 74, 2303, 2001

    被引用文献2件

  • <no title>

    ZHANG Q. W.

    J. Soc. Powder Technol., Jpn. 36, 468, 1999

    被引用文献1件

  • <no title>

    SAEKI S.

    J. Mater. Cycles Waste Manage. 3, 20, 2001

    被引用文献1件

  • Estimation of Mechanochemical Dechlorination Rate of Poly vinyl chloride

    MIO Hiroshi

    Environmental Science & Technology 36, 1344-1348, 2002

    DOI 被引用文献9件

  • <no title>

    EL-MORSI T. M.

    Environ. Sci. Technol. 34, 1018, 2000

    DOI 被引用文献1件

  • <no title>

    ZACHEIS G. A.

    J. Phys. Chem. B 103, 2142, 1999

    被引用文献1件

  • <no title>

    NANTSIS E. A.

    J. Mol. Struct. : THEOCHEM 468, 51, 1998

    DOI 被引用文献1件

  • <no title>

    NGUYEN K. A.

    J. Chem. Phys. 114, 10757, 2001

    被引用文献1件

  • <no title>

    OHKATSU Y.

    Polym. Degrad. Stab. 67, 541, 2000

    被引用文献1件

  • <no title>

    ORGAN M. G.

    J. Org. Chem. 65, 3666, 2000

    被引用文献2件

  • <no title>

    NOBLE M. A.

    Biochem. J. 351, 723, 2000

    被引用文献1件

  • <no title>

    RAGOT F.

    Synth. Met. 120, 773, 2001

    被引用文献1件

  • <no title>

    WILHELM H.

    J. Appl. Phys. 84, 6552, 1998

    被引用文献2件

  • <no title>

    SALVER-DISMA F.

    J. Power Sources 81-82, 291, 1999

    被引用文献2件

被引用文献:  1件中 1-1件 を表示

各種コード

  • NII論文ID(NAID)
    10013929839
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • NDL 記事登録ID
    6711803
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z53-B35
  • データ提供元
    CJP書誌  CJP引用  NDL  IR  J-STAGE 
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