Unoccupied Electronic State of SrTi<sub>1-<i>x</i></sub>Nb<sub><i>x</i></sub>O<sub>3</sub>Observed by Inverse-Photoemission Spectroscopy

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  • Unoccupied Electronic State of SrTi1-xNbxO3 Observed by Inverse-Photoemission Spectroscopy

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The unoccupied electronic state of Nb5+-doped SrTiO3 (SrTi1−xNbxO3) has been studied by inverse-photoemission spectroscopy (IPES). The IPES spectra exhibit three features, which correspond to the t2g- and eg-subbands of the Ti 3d state and Sr 4d state. The peak positions and bandwidths of the IPES spectra are in good agreement with the standard band calculation. The intensity of the t2g-subband decreases with increasing Nb5+ concentration. This finding indicates that the doped electron enters the bottom of the Ti 3d-induced conduction band.

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